定义Definition
布拉维格子是三维空间中所有可能的点阵类型,共 14 种。它们按 7 个晶系分类,并区分简单(P)、体心(I)、面心(F)和底心(C)等不同的格子类型。
The Bravais lattices are the 14 possible types of lattice in three-dimensional space. They are grouped into the 7 crystal systems and distinguished as primitive (P), body-centred (I), face-centred (F) or base-centred (C).
14 种格子The fourteen lattices
立方晶系有 P、I、F 三种;四方晶系有 P、I 两种;正交晶系有 P、C、I、F 四种;单斜晶系有 P、C 两种;三斜、三方(菱方 R)和六方各一种,合计 14 种。之所以没有“四方底心”或“立方底心”等,是因为它们可以等价地选取为更小的已有格子,或者会破坏该晶系应有的对称性。
The cubic system has P, I and F; tetragonal has P and I; orthorhombic has P, C, I and F; monoclinic has P and C; triclinic, trigonal (rhombohedral R) and hexagonal have one each, making 14. There is no 'base-centred tetragonal' or 'base-centred cubic' because such arrangements are equivalent to smaller lattices already listed or would break the symmetry the system requires.
由来Origin
1842 年弗兰肯海姆提出存在 15 种点阵,1848 年法国物理学家奥古斯特·布拉维指出其中两种实际相同,证明三维点阵只有 14 种。二维空间则只有 5 种布拉维格子。在布拉维格子基础上结合 32 种晶体学点群,可得到 230 种空间群。
In 1842 Frankenheim proposed 15 lattices; in 1848 the French physicist Auguste Bravais showed two of them were the same, proving there are only 14 in three dimensions. Two-dimensional space has just 5. Combining the Bravais lattices with the 32 crystallographic point groups gives the 230 space groups.
意义Significance
布拉维格子决定了衍射图的系统消光规律:例如体心格子中 h + k + l 为奇数的衍射消失,面心格子中 h、k、l 奇偶混杂的衍射消失,这是由粉末衍射确定格子类型的依据。金属铜(cF)、α-铁(cI)、氯化铯(cP)分别属于不同的立方格子。
The Bravais lattice fixes the systematic absences in a diffraction pattern: in a body-centred lattice reflections with h + k + l odd vanish, and in a face-centred lattice those with mixed odd and even h, k, l vanish, which is how powder diffraction identifies the lattice type. Copper (cF), α-iron (cI) and caesium chloride (cP) belong to different cubic lattices.
年表Timeline
- 1842
弗兰肯海姆提出 15 种点阵
Frankenheim proposes 15 lattices
- 1848
布拉维证明只有 14 种
Bravais proves there are 14
- 1891
230 种空间群推导完成
The 230 space groups are derived